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Interchannel interference in resonant Auger scattering from fixed-in-space molecules as a new technique for structure determination.

TitleInterchannel interference in resonant Auger scattering from fixed-in-space molecules as a new technique for structure determination.
AuthorsF. Gel'mukhanov and I. Minkov
CitationPhys. Rev. A 70 (2004) 32507
Doi:
Year2004
FieldX-ray Chemistry and Physics
SectionNon-Resonant X-Ray, Auger and photoelectron spectroscopies
Sub-sectionNon-resonant Auger emission
Keywords
AbstractA new method for structure determination of polyatomic molecules with equivalent atoms is suggested. The method is based on an interference pattern in the resonant Auger scattering process. This pattern is caused by interference of resonant Auger channels corresponding to core-hole localized on different equivalent atoms. The predicted effect can be observed in angular resolved electron-ion coincidence measurements or, alternatively, using the ordinary Auger technique on surface-oriented molecules.

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